From Survivor Gabon, the 17th season of Survivor is Sugar's headband. I can't remember the episode number exactly but the castaways were giving fabric to get dressed up in, Sugar turned part of her fabric into a headband which can be seen in the below pictures.
This item was obtained directly from "Sugar" aka Jessica Kiper herself, matches up to it's appearance in the episode itself and a picture of her with it before I obtained it from her.
I'm always on the hunt for Survivor items, feel free to leave a comment or check out my other items :)